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Nicole Rijs

Dr. Nicole Rijs

Postdoc
Research Unit: Physical Chemistry of Nanoscale Systems
Room: 0-230
Phone: 0721/608-26416
nicole rijsEpa7∂kit edu


Publication List

  • Rijs, N. J., González-Navarrete, P., Schlangen, M., Schwarz H. (2016): “Penetrating the Elusive Mechanism of Copper Mediated Fluoromethylation in the Presence of Oxygen via the Gas-Phase Reactivity of Well-Defined [LCuO]+ Complexes with Fluoromethanes (CH(4-n)Fn, n = 1 – 3)." In press, J. Am. Chem. Soc.
  • Rijs, N.J., Weiske, T., Schlangen, M., Schwarz, H. (2015): “Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal–1,10-Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N2 Is Not Always an “Inert” Buffer Gas.” Anal. Chem., 87, 9769–9776; Anal.Chem. 87, 11601-11601.
  • Tang, S-Y, Rijs N. J., Li J., Schlangen M., Schwarz H. (2015) “Ligand-Controlled CO2 Activation Reactions mediated by titanium hydride complexes, LTiH+ (L = Cp2, O).” Chem. Eur. J. 21, 8483–8490.
  • O'Hair, R.A.J, Rijs, N.J. (2015): "Gas Phase Studies of the Pesci Decarboxylation Reaction: Synthesis, Structure, and Unimolecular and Bimolecular Reactivity of Organometallic Ions." Acc. Chem. Res. 48, 329-340 .
  • Rijs, N.J., Weiske, T., Schlangen, M., Schwarz, H. (2014): "On divorcing isomers, dissecting reactivity, resolving gas-phase mechanisms and aryl C-X." Chem. Phys. Lett., 608, 408-424.
  • Rijs, N.J., Yoshikai, N., Nakamura, E., O'Hair, R.A.J. (2014): "Unraveling Organocuprate Complexity: Fundamental Insights into Intrinsic Group Transfer Selectivity in Alkylation Reactions."J. Org. Chem., 79, 1320 - 1334.
  • Rijs, N. J, Brookes, N.J., O'Hair, R.A.J.; Yates, B.F. (2012): "Theoretical Approaches to Estimating Homolytic Bond Dissociation Energies of Organocopper and Organosilver Compounds." J. Phys. Chem. A, 116, 8910−8917.
  • Rijs, N.J.O'Hair, R.A.J. (2012): "Forming trifluoromethylmetallates: competition between decarboxylation and C-F bond activation of group 11 trifluoroacetate complexes, [CF3CO2ML]." Dalton Trans., 41, 3395-3406.
  • Rijs, N.J., Yoshikai, N., Nakamura, E., O'Hair, R.A.J. (2012): "Gas-Phase Reactivity of Group 11 Dimethylmetallates with Allyl Iodide." J. Am. Chem. Soc., 134, 2569-2580.
  • Rijs, N.J., Sanvido, G. B., Khairallah, G.N., O'Hair, R.A.J. (2010): "Gas phase Synthesis and Reactivity of Dimethylaurate." Dalton Trans., 39, 8655-8662.
  • Rijs, N.J., O'Hair, R.A.J. (2009): "Gas-Phase Synthesis of Organoargenate Anions and Comparisons with Their Organocuprate Analogues."Organometallics, 28, 2684-2692.
  • Rijs, N., Waters, T., Khairallah, G.N., O'Hair, R.A.J. (2008): "Gas-Phase Synthesis of the Homo and Hetero Organocuprate Anions [MeCuMe] -, [EtCuEt]- and [MeCuR]-." J. Am. Chem. Soc., 130, 1069-1079.