Talk given by

Prof. Cheng-Yong Su

Sun Yat-Sen University

Lehn Insititute of Functional Materials

Guangzhou, China

Abstract:

Coordination supramolecular engineering is targeted for the design, assembly, modification and application of metal-organic materials (MOMs) with well-defined structures by using kinetically or thermodynamically versatile metal-ligand interactions as driving forces, among which metal-organic frameworks (MOFs) and metal-organic cages (MOCs) have drawn much attention. One interesting feature of MOFs and MOCs is that they both can provide confined chemical space competent for catalysis, reminiscent of natural enzyme. In this lecture, I will report our recent work on coordination assembly of MOCs as supramolecular reactors, coordination interspace engineering of MOFs as crystalline reactors, and construction of nanoscale hierarchical porous MOFs (HPMOFs) as nanoreactors.

Reference

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2. 2) M. Pan, K. Wu, J.-H. Zhang, and C.-Y. Su, Coord. Chem. Rev. 2019, 378, 333.
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4. 4) Y. Wang, H. Cui, Z.-W. Wei, H.-P. Wang, L. Zhang, C.-Y. Su, Chem. Sci. 2017, 8, 775.
5. 5) J. Teng, M. Chen, Y. Xie, D. Wang, J.-J. Jiang, G. Li, H.-P. Wang, Y. Fan, Z.-W. Wei, C.-Y. Su, Chem. Mater. 2018, 30, 6458.
6. 6) S. Wang, Y. Fan, J. Teng, Y.-Z. Fan, J.-J. Jiang, H.-P. Wang, H. Grützmacher, D. Wang, C.-Y. Su, Small 2016, 12, 5702.
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8. 8) Guo, Y.-W. Xu, K. Li, L.-M. Xiao, S. Chen, K. Wu, X.-D. Chen, Y.- Z. Fan, J.-M. Liu, C.-Y. Su, Angew. Chem. Int. Ed. 2017, 56, 3852.